ENDO-1-NAPHTHYL KWON [2.2.1] BICYCLIC PH

Code: 798436-100MG D2-231

Application

The bicyclic, chiral phosphine was developed by the Kwon Research Group. Its initial applications were for asymmetric [3+2] annulation between allenes and imines ...


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€123.19 100MG
€151.52 inc. VAT
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Application

The bicyclic, chiral phosphine was developed by the Kwon Research Group. Its initial applications were for asymmetric [3+2] annulation between allenes and imines as well as the first examples of phosphine-catalyzed asymmetric syntheses of 1,2,3,5-substituted pyrrolines. Along with nucleophilic organocatalysis, the P-chiral phosphines may also find utility in asymmetric transition-metal catalysis.

Other Notes

Hydroxyproline-Derived Pseudoenantiomeric [2.2.1] Bicyclic Phosphines: Asymmetric Synthesis of (+)- and (-)-PyrrolinesTechnology Spotlight- Kwon Phosphines: P-Chiral Monodentate Phosphines from HydroxyprolineAldrichimica Acta Review- Nucleophilic Chiral Phosphines: Powerful and Versatile Catalysts for Asymmetric Annulations

Packaging

100 mg in glass bottle

formpowder
InChI keyRGHUOMJULXTHPX-UHFFFAOYSA-N
InChI1S/C22H22NO2PS/c1-16-9-11-20(12-10-16)27(24,25)23-14-19-13-18(23)15-26(19)22-8-4-6-17-5-2-3-7-21(17)22/h2-12,18-19H,13-15H2,1H3
Quality Level100
SMILES stringO=S(N1C[C@H]2[P@@](C3=CC=CC4=C3C=CC=C4)C[C@@H]1C2)(C5=CC=C(C)C=C5)=O
storage conditionunder inert gas
storage temp.2-8°C
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